Pt(II)-activated coupling of aminoethylferrocene with benzonitrile. A facile access route to a new redox-active bis(ferrocenyl-amidine) anion sensor.

نویسندگان

  • Daniel Nieto
  • Ana Ma González-Vadillo
  • Sonia Bruña
  • César J Pastor
  • Angel E Kaifer
  • Isabel Cuadrado
چکیده

A new heterometallic electroactive compound having the ferrocenyl moiety attached to the platinum atom through an amidine functionality has been prepared via Pt(II)-mediated nucleophilic addition of β-aminoethylferrocene to a benzonitrile ligand. This neutral receptor shows remarkable electrochemical anion-sensing redox response to H(2)PO(4)(-).

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عنوان ژورنال:
  • Chemical communications

دوره 47 37  شماره 

صفحات  -

تاریخ انتشار 2011